Trans4m S Skeletal Isomerization Process

LyondellBasell, applying Trans4m S technology, is the largest producer in the world of isobutylene. Available for license, Trans4m S technology is a fixed-bed reactor, catalytic process, utilizing highly selective tailored zeolite-based catalysts for the near equilibrium conversion of normal butenes to isobutene, or normal pentenes to isoamylenes.

The proprietary catalyst used in the Trans4m S process, Z-870, operates at reduced temperatures. It also enables very high conversion rates and a very simple process configuration to achieve leading investment and operating costs.

Safety and Environment

  • LyondellBasell’s process technologies have a safety record among the best in the industry
  • Very low energy consumption
  • Non-hazardous products and materials used and produced

Catalyst and process technology highlights

  • Highly selective zeolite-based catalyst system
  • Exceptionally high process yields
  • Near equilibrium conversion to iso-butenes or isoamylenes
  • Long catalyst cycle time
  • In-situ efficient regeneration for coke removal
  • Non-fouling process

World-scale and proven

  • Single-line, world-scale capacities greater than 600 kt/a can be provided
  • Successfully licensed around the globe
  • LyondellBasell has operated Trans4m technology at its Channelview, Texas, USA, site since 1995

Economics

  • Low investment and operating costs possible due to moderate operating conditions and simple plant configuration
  • Low incremental costs for increased MTBE production

Highlights

Process technology for the skeletal isomerization of C4 or C5 olefins using a highly selective, long-life catalyst to achieve near equilibrium conversion to isobutylene and isoamylenes